33 1001 C. Michael Volk J.W. Goethe University Frankfurt, Institute for Meteorology and Geophysics; e-mail: M.Volk@meteor.uni-frankfurt.de HAGAR, M-55 GEOPHYSICA EUPLEX 1 1 2003 01 19 2004 07 29 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 14 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) CFC-12 MIXING RATIO (PPT) CFC-12 ERROR 1-sd (PPT) CFC-11 MIXING RATIO (PPT) CFC-11 ERROR 1-sd (PPT) Halon 1211 MIXING RATIO (PPT) Halon 1211 ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) 4 corrected for time delay of inlet, drift of in-flight standard, and variable N2O contamination using nonlinear laboratory calibration curve through 2 in-flight standards using Gauss peak fitting for CH4, F12, and H1211 errors are statistical precision errors (1 sd) plus estimated systematic errors of 3 ppb for N2O and 5 ppt for F12; for absolute accuracy add ~1% 1 GMTs N2O N2Oe F12 F12e F11 F11e H1211 H1211e CH4 CH4e SF6 SF6e H2 H2e 49456 315.6 5.5 534.5 6.3 255.7 2.0 3.79 0.29 1763 44.0 5.37 0.15 520.4 11.0 49547 311.3 5.4 521.0 6.3 246.3 2.0 3.40 0.29 1751 43.4 5.13 0.14 545.1 11.4 49638 306.3 5.3 513.7 6.3 239.8 2.1 3.22 0.28 1726 42.1 5.13 0.14 549.3 11.5 49729 300.7 5.3 504.7 6.4 234.5 2.2 3.22 0.28 1700 40.7 5.04 0.14 541.9 11.4 50002 304.2 5.4 513.1 6.3 237.5 2.1 3.70 0.29 1719 41.3 5.17 0.14 552.3 11.5 50093 304.4 5.4 517.0 6.3 241.9 2.1 3.54 0.29 1706 40.5 5.23 0.14 551.4 11.5 50184 296.4 5.3 501.9 6.4 227.0 2.3 3.36 0.29 1645 37.6 5.10 0.14 545.8 11.4 50275 293.1 5.3 500.0 6.4 224.2 2.4 3.22 0.28 1633 36.9 5.25 0.14 547.1 11.4 50548 276.3 4.6 467.5 6.5 198.6 2.8 2.69 0.26 1560 20.8 4.64 0.11 552.4 13.9 50639 274.7 4.6 466.1 6.5 197.4 2.9 2.91 0.27 1499 19.4 4.74 0.11 554.4 14.0 50730 268.2 4.5 453.9 6.6 186.8 3.0 2.70 0.26 1521 19.9 4.61 0.11 550.7 13.9 50821 261.0 4.4 440.9 6.6 177.1 3.1 2.34 0.26 1506 19.6 4.49 0.11 553.5 14.0 51094 244.3 4.2 406.2 6.7 151.0 2.6 2.10 0.26 1448 18.4 4.61 0.11 568.1 14.6 51185 244.9 4.2 405.4 6.7 150.1 2.6 1.93 0.26 1443 18.3 4.41 0.10 555.0 14.2 51276 223.4 4.0 364.5 6.8 121.7 2.6 1.77 0.26 1366 16.6 4.26 0.10 551.8 14.2 51367 192.6 3.6 310.1 7.0 88.0 2.4 1.21 0.26 1232 14.0 4.13 0.10 563.5 14.6 52186 144.7 3.2 220.6 7.2 33.8 1.9 0.72 0.26 1093 11.1 3.70 0.11 576.9 15.7 52277 147.5 3.2 224.7 7.2 36.6 1.9 0.81 0.26 1091 11.0 3.93 0.11 585.1 16.0 52368 151.2 3.2 231.2 7.2 39.4 1.9 0.93 0.26 1094 11.0 3.90 0.11 578.0 15.6 52459 155.1 3.3 238.7 7.2 44.6 2.0 0.96 0.26 1102 11.0 3.79 0.11 560.8 14.9 52732 147.2 3.2 222.6 7.2 34.8 1.9 0.58 0.26 1087 10.8 3.93 0.13 582.6 13.8 52823 151.6 3.2 229.0 7.2 37.9 1.9 0.71 0.26 1105 10.9 3.76 0.12 560.4 13.2 52914 146.8 3.2 222.6 7.2 34.4 1.9 0.78 0.26 1068 10.7 3.68 0.12 562.0 13.2 53005 149.0 3.2 225.2 7.2 37.8 1.9 0.81 0.26 1081 10.8 3.71 0.12 564.6 13.2 53279 141.3 3.2 209.9 7.2 31.1 1.9 0.66 0.26 1050 15.5 3.60 0.12 577.2 13.5 53370 142.9 3.2 214.0 7.2 31.0 1.9 0.64 0.26 1058 15.4 3.78 0.12 563.8 13.1 53461 147.5 3.2 221.8 7.2 32.7 1.9 0.86 0.26 1072 15.2 3.76 0.12 571.6 13.3 53551 142.8 3.2 213.9 7.2 32.0 1.9 0.65 0.26 1066 15.2 3.81 0.13 562.0 13.1 53824 146.1 3.2 221.3 7.2 36.6 1.9 0.60 0.25 1095 14.6 3.61 0.10 566.4 11.5 53915 150.4 3.2 227.7 7.1 36.3 1.9 0.69 0.25 1107 14.5 9999 999 571.1 11.6 54006 142.5 3.2 214.7 7.1 30.9 1.9 0.93 0.26 1070 14.7 3.57 0.10 563.4 11.4 54097 144.1 3.2 216.6 7.1 33.6 1.9 0.69 0.25 1083 14.5 3.70 0.11 552.6 11.3 54370 151.5 3.2 230.3 7.1 39.5 1.9 0.89 0.26 1103 13.6 3.75 0.11 567.3 11.4 54462 149.7 3.2 226.0 7.1 35.8 1.9 0.67 0.25 1108 13.7 3.62 0.10 563.1 11.4 54552 149.0 3.2 227.1 7.1 36.6 1.9 0.96 0.26 1086 13.9 3.72 0.11 557.1 11.3 54644 146.6 3.2 224.1 7.1 36.3 1.9 0.82 0.26 1082 13.9 3.40 0.10 549.8 11.2 54916 144.7 3.2 223.3 7.0 35.6 1.9 0.64 0.25 1059 14.3 3.68 0.10 563.8 13.1 55007 146.5 3.2 224.6 7.0 34.5 1.9 0.64 0.25 1072 14.3 3.69 0.10 557.9 12.9 55098 146.8 3.2 226.2 7.0 34.7 1.9 0.84 0.25 1077 14.4 3.55 0.10 555.6 12.9 55190 144.3 3.2 221.7 7.0 35.7 1.9 0.89 0.25 1057 14.5 3.68 0.10 558.9 13.0 55462 148.7 3.2 228.0 8.2 37.3 1.9 0.74 0.25 1079 10.6 3.69 0.10 566.0 13.2 55554 150.2 3.2 228.5 8.2 35.8 1.9 0.61 0.25 1080 10.6 3.72 0.10 560.8 13.1 55645 150.1 3.2 224.9 8.2 33.9 1.9 0.86 0.25 1078 10.6 3.64 0.10 564.5 13.2 55736 153.9 3.2 231.8 8.1 39.4 2.0 0.87 0.25 1061 10.5 3.63 0.10 565.2 13.2 56008 155.0 3.2 244.1 8.1 43.1 2.0 0.78 0.25 1106 11.0 3.96 0.10 564.4 11.8 56099 164.3 3.2 258.6 8.0 50.3 2.0 0.83 0.25 1124 11.1 3.76 0.10 558.5 11.7 56190 178.1 3.3 280.1 7.9 60.8 2.0 1.21 0.25 1176 11.6 3.82 0.10 557.7 11.6 56281 189.4 3.3 300.8 7.7 74.0 2.1 1.19 0.25 1215 11.9 4.05 0.10 556.4 11.6 56554 240.5 3.6 388.3 9.0 143.6 3.1 2.05 0.26 1421 14.6 4.30 0.11 536.7 11.3 56645 254.3 3.7 413.6 8.4 163.7 3.0 2.38 0.26 1445 14.8 4.30 0.11 536.6 11.3 56736 270.7 3.8 444.1 7.7 191.3 2.7 3.13 0.26 9999 999 5.09 0.12 531.3 11.3 56827 278.9 3.9 473.4 7.2 205.8 2.5 3.02 0.26 9999 999 5.10 0.12 564.2 11.8 57100 290.6 3.8 496.2 7.0 216.7 2.4 3.12 0.39 1647 16.5 5.00 0.12 567.1 11.1 57191 289.3 3.8 491.7 7.0 214.1 2.4 2.91 0.38 1633 16.3 4.97 0.12 562.1 11.1 57282 287.7 3.8 487.1 7.0 211.2 2.5 2.53 0.36 1630 16.3 4.69 0.12 563.3 11.1 57373 283.2 3.7 476.7 7.0 206.6 2.5 9999 999 1599 15.9 4.71 0.12 561.9 11.1 57646 266.6 3.6 441.9 7.4 183.2 3.1 2.91 0.38 1520 15.7 4.63 0.11 554.8 11.0 57737 245.5 3.5 404.1 8.0 152.9 3.3 1.26 0.30 1445 15.3 4.23 0.10 541.3 10.9 57828 222.9 3.4 363.7 8.9 120.9 3.3 1.16 0.30 1328 15.1 4.21 0.10 541.0 10.9 57919 193.4 3.3 314.8 10.2 85.7 3.0 0.64 0.28 1204 15.4 4.02 0.10 553.3 11.1 58192 180.2 3.3 290.6 11.2 73.0 2.9 9999 999 1171 15.7 4.00 0.11 573.5 10.3 58284 153.6 3.2 242.7 12.7 45.4 2.4 9999 999 1097 16.2 4.02 0.11 577.7 10.3 58375 145.6 3.2 227.0 13.3 39.3 2.3 0.25 0.27 1051 16.6 3.85 0.11 574.4 10.3 58466 135.9 3.1 208.1 14.1 32.5 2.2 0.36 0.27 1005 17.0 3.82 0.11 576.9 10.3 58740 105.0 3.1 152.3 8.7 17.1 1.9 9999 999 910 14.2 3.70 0.12 573.7 10.3 58831 96.9 3.1 138.0 8.9 13.1 1.9 9999 999 865 14.4 3.76 0.12 557.1 10.2 58922 91.8 3.1 131.6 8.9 11.1 1.9 0.17 0.26 854 14.5 3.52 0.12 564.8 10.3 59013 92.7 3.1 132.5 8.9 11.8 1.9 0.16 0.26 858 14.4 3.74 0.13 566.0 10.3 59286 97.6 3.1 139.8 8.8 14.7 1.9 9999 999 875 14.1 3.52 0.14 574.1 22.6 59377 86.6 3.1 120.3 9.0 9.7 1.9 9999 999 844 14.3 3.73 0.15 552.8 21.3 59468 85.6 3.1 120.2 9.0 11.0 1.9 -0.13 0.25 827 14.4 3.71 0.15 568.7 22.3 59559 83.1 3.1 115.8 9.0 9.4 1.9 -0.08 0.25 826 14.3 3.43 0.14 560.7 21.8 59832 85.4 3.1 122.1 7.8 11.9 1.9 9999 999 848 12.3 3.65 0.15 561.5 21.7 59923 85.3 3.1 118.8 7.8 10.2 1.9 9999 999 838 12.4 3.68 0.15 550.9 20.9 60014 83.9 3.1 117.0 7.8 9.7 1.9 -0.11 0.25 822 12.5 3.65 0.14 551.4 20.9 60105 82.5 3.1 115.0 7.9 9.5 1.9 -0.09 0.25 824 12.5 3.75 0.15 555.2 21.0 60378 85.6 3.1 120.8 7.8 10.8 1.9 9999 999 862 12.4 3.74 0.13 558.9 22.9 60560 84.2 3.1 120.7 7.7 9.9 1.9 -0.32 0.25 839 12.6 3.75 0.13 557.8 23.0 60651 85.3 3.1 123.5 7.7 10.8 1.9 -0.15 0.25 836 12.6 3.63 0.13 556.5 23.0 60924 115.3 3.2 174.0 8.2 25.6 1.9 9999 999 951 12.8 3.88 0.13 573.7 24.3 61015 116.9 3.3 173.2 8.2 25.1 1.9 9999 999 951 12.7 3.89 0.13 564.8 23.8 61106 112.6 3.2 168.2 8.3 22.5 1.9 -0.12 0.25 930 12.8 3.75 0.13 561.5 23.6 61197 97.3 3.3 143.3 8.4 15.2 1.9 -0.32 0.25 893 12.9 3.63 0.13 557.9 23.4 61470 106.2 3.2 154.3 8.5 19.3 1.9 9999 999 937 12.7 3.74 0.12 576.3 12.8 61561 99.2 3.3 141.4 8.6 15.4 1.9 9999 999 908 12.8 3.84 0.12 569.1 12.6 61652 107.6 3.2 159.0 8.5 19.4 1.9 0.23 0.26 958 12.6 3.78 0.12 564.0 12.5 61743 127.3 3.3 189.9 8.3 27.2 1.9 0.32 0.27 1009 12.6 3.70 0.12 566.5 12.6 62016 149.5 3.5 224.8 7.2 38.2 2.0 0.05 0.26 1092 16.4 3.90 0.10 573.3 12.9 62107 154.6 3.5 238.0 7.2 42.8 2.0 9999 999 1113 16.3 4.01 0.10 574.7 13.0 62197 148.5 3.5 227.7 7.2 41.8 2.0 0.36 0.27 1080 16.7 3.94 0.10 570.9 12.9 62288 147.3 3.5 227.7 7.2 43.8 2.0 0.11 0.26 1063 16.9 3.77 0.10 558.5 12.6 63105 299.2 4.1 505.3 6.3 229.5 3.6 3.52 0.31 1681 46.3 4.79 0.29 570.0 20.5 63196 303.1 4.1 517.4 6.3 240.2 3.3 3.12 0.30 1693 46.7 5.08 0.32 551.5 19.1 63287 287.4 4.0 487.7 6.4 214.4 4.1 2.63 0.29 1600 41.8 4.62 0.27 553.6 19.1 63379 290.7 4.0 496.7 6.3 221.9 3.8 2.82 0.29 1626 42.9 4.49 0.25 539.2 18.2 63651 306.5 5.3 523.2 6.3 240.5 4.3 3.38 0.36 1688 72.3 5.21 0.58 557.3 27.1 63743 307.8 5.3 526.0 6.2 247.4 4.4 3.76 0.38 1725 75.8 4.82 0.51 542.9 25.8 63834 310.1 5.4 527.5 6.2 251.7 4.5 3.59 0.37 1701 73.9 5.14 0.58 534.7 25.1 63925 313.4 5.4 533.9 6.2 259.6 4.9 4.30 0.40 1794 82.5 5.17 0.60 523.3 24.2 64197 317.0 5.4 543.9 6.2 258.9 5.0 9999 999 1862 90.6 5.82 0.80 534.7 25.5 64288 316.2 5.4 539.2 6.2 256.0 5.0 4.19 0.40 1859 91.0 5.46 0.73 523.7 24.7 64379 316.0 5.4 535.2 6.2 252.9 4.9 4.26 0.40 1891 94.9 5.59 0.78 515.5 24.2 64470 312.8 5.4 535.6 6.2 255.3 5.1 4.50 0.41 1843 91.1 5.93 0.89 490.4 22.4 64742 312.8 4.1 540.9 8.6 253.3 3.4 3.59 0.30 1882 59.4 5.63 0.50 480.7 11.3 64833 312.7 4.1 539.3 8.6 252.7 3.5 3.91 0.31 1864 58.1 5.31 0.45 486.7 11.3